87306-90-9

Upstream product

• 87306-76-1 (4S,5S)-2-(6,2'-Dimethoxy-biphenyl-2-yl)-4-methoxymethyl-5-phenyl-4,5-dihydro-oxazole 
• 94235-68-4 (4S,5S)-2-(2,3-Dimethoxy-phenyl)-4-methoxymethyl-5-phenyl-4,5-dihydro-oxazole 
• 1521-39-7 2,3-dimethoxybenzamide 
• 1521-38-6 2,3-dimethoxybenzoic acid 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 87306-80-7 (1S,2S)-2-[(6,2'-Dimethoxy-biphenyl-2-ylmethyl)-amino]-3-methoxy-1-phenyl-propan-1-ol 
• 87306-80-7 (1R,2R)-2-[(6,2'-Dimethoxy-biphenyl-2-ylmethyl)-amino]-3-methoxy-1-phenyl-propan-1-ol 
• 7169-06-4 2,3-dimethoxybenzoyl chloride 

Downstream Products

• 87306-98-7 [(1S,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methoxymethyl-2-phenyl-ethyl]-[1-(6,2'-dimethoxy-biphenyl-2-yl)-meth-(E)-ylidene]-amine 
• 87306-84-1 2',6-dimethoxy-(1,1'-biphenyl)-2-carboxaldehyde 
• 87306-94-3 C₃₁H₄₂ClNO₄Si 
• 87306-98-7 [(1R,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methoxymethyl-2-phenyl-ethyl]-[1-(6,2'-dimethoxy-biphenyl-2-yl)-meth-(E)-ylidene]-amine 
• 87306-94-3 C₃₁H₄₂ClNO₄Si 

Relevant academic research and scientific papers

Enantioselective Synthesis of 2,2',6-Trisubstituted Biphenyls

A general procedure is described for the synthesis of chiral biphenyls via nucleophilic aromatic substitution of an o-methoxy group by an aryl Grignard reagent with an oxazoline as a chiral auxiliary.

Reductive Cleavage of Aryl Oxazolines to Benzaldehydes and Substituted Toluenes

Aryl oxazolines have been converted to their corresponding benzaldehydes and toluenes by several routes by passing through the intermediate amino alcohols.The transformations proceeded under mild conditions and were shown to be generally applicable to a variety of substitutions on the aromatic nucleus.