87308-15-4Relevant academic research and scientific papers
Methyl Deuteration Reactions in Vinylporphyrins: Protoporphyrins IX, III, and XIII
Smith, Kevin M.,Parish, Daniel W.,Inouye, Warren S.
, p. 666 - 671 (2007/10/02)
Base-catalyzed deuteration of the methyl groups in protoporphyrin IX dimethyl ester (1) proceeds with differential deuteration; rate of deuteration, as measured by NMR spectroscopy of reaction products, follows the order 3-Me > 1-Me >5-Me >8-Me.A simple q
Neighboring Group Participation in the Pyrrole Series
Smith, Kevin M.,Martynenko, Zoya,Pandey, Ravindra K.,Tabba, Hani D.
, p. 4296 - 4302 (2007/10/02)
With use of proton and carbon-13 NMR spectroscopy of deuterium- and carbon-13-labeled substrates, the transformation of certain (2-hydroxyethyl)pyrroles (4, 18, 21) into the corresponding (2-haloethyl)pyrroles (using thionyl chloride/pyridine or triphenyl
