87314-12-3

Basic information

• Product Name: Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate
• Synonyms: Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate
• CAS NO: 87314-12-3
• Molecular Formula: C28H38Cl6NNiS4
• Molecular Weight: 788.27942
• Product Categories: electronic
• Mol File: 87314-12-3.mol
• Article Data: 0

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate(CAS DataBase Reference)
• NIST Chemistry Reference: Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate(87314-12-3)
• EPA Substance Registry System: Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate(87314-12-3)

Safety Data

• Hazardous Substances Data: 87314-12-3(Hazardous Substances Data)

Usage

Description

Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate, with the chemical formula [(CH3)3N+][Ni(C6H2Cl3S2)2]-, is a complex organometallic compound that features a nickel center coordinated to two 1,2-benzenedithiolate ligands, each substituted with three chlorine atoms at the 3, 4, and 6 positions. Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate is characterized by its unique electronic and structural properties, which make it suitable for various applications in chemical synthesis and as a catalyst.

Uses

Used in Chemical Synthesis:
Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate is used as a catalyst in the synthesis of bis(dimethylphenyl)ethane, a compound with potential applications in the production of polymers and other organic materials. Its catalytic activity is attributed to the ability of the nickel center to facilitate key reaction steps, leading to the formation of the desired product.
Used in Photochemistry:
In the field of photochemistry, Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate serves as a quenching agent for singlet oxygen. Singlet oxygen is a highly reactive species that can participate in various chemical reactions, and controlling its reactivity is crucial for the success of certain photochemical processes. The nickel complex effectively interacts with singlet oxygen, reducing its lifetime and preventing unwanted side reactions.
Used in Analytical Chemistry:
Due to its unique optical and electronic properties, Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate can be employed as a sensitive probe in analytical chemistry. It can be used to detect and quantify specific analytes by monitoring changes in its absorption or emission properties upon interaction with the target molecules.
Used in Material Science:
The organometallic nature of Tetrabutylammonium bis(3,4,6-trichloro-1,2-benzene-dithiolato)nickelate makes it a promising candidate for the development of new materials with tailored properties. For instance, it can be incorporated into the design of metal-organic frameworks (MOFs) or used as a precursor for the synthesis of novel coordination polymers with potential applications in catalysis, gas storage, or sensing.