87319-20-8Relevant academic research and scientific papers
REARRANGEMENT DES PHOSPHOLES-1H NON SUBSTITUES SUR LE PHOSPHORE EN PHOSPHOLES-2H. SYNTHESE DES DIMERES ET DES COMPLEXES DE PHOSPHOLES-2H
Charrier, C.,Bonnard, H.,Lauzon, G. de,Holand, S.,Mathey, F.
, p. 51 - 54 (2007/10/02)
The protonation of phosphoryl anions yields P-unsubsituted 1H-phospholes.Between -50 deg C and -20 deg C, the 1H-phospholes rearrange to give 2H-phospholes which instantly dimerize.The hydrolysis of 3,4-dimethylphospholyllithium W(CO)5- or Cr(CO)5- complexed leads to stable 3,4-dimethyl-2H-phosphole complexes.
