873424-50-1Relevant academic research and scientific papers
RhI-catalyzed cycloisomerization of vinyl bicyclopropyl compounds to azabicyclo[3.2.2]nona-2, 8-dienes
Kim, Sun Young,Kang, Youn K.,Chung, Young Keun
supporting information; experimental part, p. 5310 - 5313 (2010/09/10)
(Figure Presented) Important class: Nitrogen-containing heterobicycles are an important structural motif ubiquitous in natural alkaloids. We found that azabicyclo[3.2.2]nona-2, 8-dienes can be synthesized from vinyl bicyclopropropyl derivatives in the pre
Rhodium N-heterocyclic carbene-catalyzed [4 + 2] and [5 + 2] cycloaddition reactions
Lee, Sang Ick,Park, Se Yeoun,Park, Ji Hoon,Jung, Il Gu,Choi, Soo Young,Chung, Young Keun,Lee, Bun Yeoul
, p. 91 - 96 (2007/10/03)
A rhodium complex of N-heterocyclic carbene (NHC) has been developed for intra- and intermolecular [4 + 2] and intramolecular [5 + 2] cycloaddition reactions. This is the first use of a transition-metal NHC complex in a Diels-Alder-type reaction. For the
