873430-07-0Relevant academic research and scientific papers
Intramolecular ene reaction of epoxyallylsilanes: Synthesis of allyl- and vinylsilane-functionalized cyclohexanols
Barbero, Asuncion,Castreno, Pilar,Fernandez, Gloria,Pulido, Francisco J.
, p. 10747 - 10752 (2005)
Epoxyallylsilanes bearing the bulky tert-butyldiphenylsilyl group undergo an uncommon tandem rearrangement-cyclization process upon treatment with Lewis acids. Two pathways for the carbonyl ene reaction are observed: one leading to allylsilane-cyclohexano
