873438-24-5

Basic information

• Product Name: (-)-(2R,3R,4R,5R)-2-(tert-butyldimethylsilyloxymethyl)-3,4-epoxy-5-phenyl-4-(p-tolylsulfonyl)tetrahydrofuran
• Synonyms: (-)-(2R,3R,4R,5R)-2-(tert-butyldimethylsilyloxymethyl)-3,4-epoxy-5-phenyl-4-(p-tolylsulfonyl)tetrahydrofuran
• CAS NO: 873438-24-5
• Molecular Weight: 460.667
• Mol File: 873438-24-5.mol

Chemical Properties

• CAS DataBase Reference: (-)-(2R,3R,4R,5R)-2-(tert-butyldimethylsilyloxymethyl)-3,4-epoxy-5-phenyl-4-(p-tolylsulfonyl)tetrahydrofuran(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(2R,3R,4R,5R)-2-(tert-butyldimethylsilyloxymethyl)-3,4-epoxy-5-phenyl-4-(p-tolylsulfonyl)tetrahydrofuran(873438-24-5)
• EPA Substance Registry System: (-)-(2R,3R,4R,5R)-2-(tert-butyldimethylsilyloxymethyl)-3,4-epoxy-5-phenyl-4-(p-tolylsulfonyl)tetrahydrofuran(873438-24-5)

Safety Data

• Hazardous Substances Data: 873438-24-5(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 873438-22-3 tert-Butyl-dimethyl-[(2S,5R)-5-phenyl-4-(toluene-4-sulfonyl)-2,5-dihydro-furan-2-ylmethoxy]-silane 

Downstream Products

• 873438-43-8 (+)-(2R,5S)-5-(tert-butyldimethylsilyloxymethyl)-2-phenyl-3-oxotetrahydrofuran 

Relevant articles and documents

Reductive cleavage of tetrahydrofuryl sulfur-substituted oxiranes: Application to the formal synthesis of Kumausyne and Kumausallene

Readily available sulfnyl and sulfonyl tetrahydrofuran methanol derivatives have been transformed efficiently into a variety of substituted tetrahydrofuryl alcohols by treatment with (PhSe)2 in the presence of an excess of NaBH4. Alt