873441-41-9

Upstream product

• 873441-49-7 Acetic acid (3aS,4R,6S,7R,7aR)-6-tert-butylsulfanyl-7-hydroxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-ylmethyl ester 
• 1079-66-9 chloro-diphenylphosphine 
• 4163-60-4 β-D-galactose peracetate 
• 79763-12-5 tert-butyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside 
• 79763-15-8 (2S,3R,4S,5R,6R)-2-tert-Butylsulfanyl-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol 
• 873441-45-3 (3aS,4R,6S,7R,7aR)-6-tert-Butylsulfanyl-4-hydroxymethyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol 

Relevant academic research and scientific papers

Pseudo enantiomeric mixed S/P ligands derived from carbohydrates for the 1,4-addition of phenyl boronic acid to cyclohexenone

The application of phosphinite-thioglycosides and phosphine-thioglycosides ligands in Rh(i)-catalyzed 1,4-addition of phenylboronic acid to cyclohexenone is reported. Among the ligands tested, phosphinite-thioglycoside 3 and phosphine-thioglycoside 10, be

P/S ligands derived from carbohydrates in Rh-catalyzed hydrosilylation of ketones

Reported is the synthesis of a number of diastereomerically pure cationic Rh(i)-complexes I starting from phosphinite thioglycosides. These complexes were used in the asymmetric hydrosilylation of prochiral ketones. The reactivity and enantioselectivity o

Mixed S/P ligands from carbohydrates: Synthesis and utilization in asymmetric catalysis

New chiral mixed sulfur/phosphorus ligands derived from carbohydrates are reported. These ligands were found to be efficient catalyst precursors for palladium-catalyzed asymmetric substitution of 1,3-diphenylpropenyl acetate with dimethyl malonate or benz

Phosphinite thioglycosides derived from natural D-sugars as useful P/S ligands for the synthesis of both enantiomers in palladium-catalyzed asymmetric substitution

Phosphinite thioglycosides I for which a modular synthetic approach is reported, were found highly efficient catalyst precursors for palladium(0)-catalyzed asymmetric substitution. Both enantiomers of the allylated products have been obtained with high ee