87345-09-3

Upstream product

• 615-36-1 2-bromoaniline 
• 583-55-1 1-Bromo-2-iodobenzene 
• 74-88-4 methyl iodide 
• 67242-17-5 2,2’-dibromodiphenylamine 

Downstream Products

• 1484-12-4 N-methylcarbazole 
• 1591668-97-1 C₁₉H₁₉N 
• 1427210-35-2 N,N-bis(2-formylphenyl)methylamine 
• 52249-32-8 N-methyldibenzazepine 
• 1427210-31-8 N,N-bis(2-vinylphenyl)methylamine 
• 144776-63-6 N-methyl-B-mesityldibenzo-1,4-azaborinine 

Relevant academic research and scientific papers

Scalable Synthesis of Acridinium Catalysts for Photoredox Deuterations

The continuous development of photocatalytic methods incentivizes the design of organic catalysts to complement the frequently used and precious polypyridyl transition metal systems. Herein, a scalable synthesis of suitable acridinium dyes and their appli

Pd-Catalyzed Autotandem Reactions with N-Tosylhydrazones. Synthesis of Condensed Carbo- and Heterocycles by Formation of a C-C Single Bond and a C-C Double Bond on the Same Carbon Atom

A new Pd-catalyzed autotandem reaction is introduced that consists of the cross-coupling of a benzyl bromide with a N-tosylhydrazone followed by an intramolecular Heck reaction with an aryl bromide. During the process, a single and a double C-C bond are formed on the same carbon atom. Two different arrangements for the reactive functional groups are possible, rendering great flexibility to the transformation. The same strategy led to 9-methylene-9H-fluorenes, 9-methylene-9H-xanthenes, 9-methylene-9,10-dihydroacridines, and also dihydropyrroloisoquinoline and dihydroindoloisoquinoline derivatives.

Monobenzofused 1,4-azaborines: Synthesis, characterization, and discovery of a unique coordination mode

We report the first general synthesis of boron-substituted monobenzofused 1,4-azaborines using ring-closing metathesis of an enamine-containing diene as a key synthetic strategy. As part of our investigations, we discovered that the B-C3 moiety in a 1,4-a

Synthesis of dibenzoheteropines of group 13-16 elements via ring-closing metathesis

The ring-closing metathesis (RCM) of bis(2-vinylphenyl)silanes in the presence of the second-generation Hoveyda-Grubbs catalyst in toluene at 100 C afforded dibenzo[b,f]silepines in excellent yields. Other dibenzoheteropines of group 13-16 elements were also prepared via the RCM of the corresponding heteroatom-tethered dienes.

Development of a catalytic electron transfer system mediated by transition metal ate complexes: Applicability and tunability of electron-releasing potential for organic transformations

We have developed a catalytic electron transfer (ET) system composed of a transition metal ate complex (Me3M(II)Li; M = Co(II), Mn(II), Fe(II)) and magnesium. This system (catalytic Me3M(II)Li/Mg) turned out to be effective for various ET reactions, such as the desulfonylation of N-phenylsulfonyl amides, and others (the chemoselective cleavage of O-allyl groups, the reduction of nitro groups, the partial reduction of diketones, and the reductive coupling of diphenyliodonium salt). The ET ability of this system can be tuned by changing the ligands of the ate complexes. This tunability was experimentally and electrochemically demonstrated: alkoxy-ligated and dianion-type ET ate complexes showed attenuated and enhanced reducing abilities, respectively. The modification of the ET abilities was evaluated by means of electrochemical measurements and chemical reactions. These results provide a basis for the design of various tailor-made ET ate complexes.