873544-27-5

Upstream product

• 13139-17-8 N-(Benzyloxycarbonyloxy)succinimide 
• 212970-87-1 t-butyl (2S)-N-t-butoxycarbonyl-3,4-dehydroprolinate 
• 170850-75-6 BOC-Hyp-OtBu 
• 13726-69-7 (2S,4R)-4-hydroxy-1-[(2-methylpropan-2-yl)oxycarbonyl]pyrrolidine-2-carboxylic acid 
• 873544-26-4 tert-butyl (2S,2'R,3R,4R)-N_α-Boc-3,4-(N,N-dibenzylaminomethano)prolinate 
• 873544-15-1 tert-butyl (2S)-N-Boc-4-iodoprolinate 

Downstream Products

• 873544-20-8 methyl (2S,2'R,3R,4R)-N_α-Boc-3,4-(Z-aminomethano)prolylglycinate 
• 873544-16-2 tert-butyl (2S,2'R,3R,4R)-N-Fmoc-glycyl-3,4-(Z-aminomethano)prolinate 
• 873544-28-6 (2S,2'R,3R,4R)-N_α-Boc-3,4-(Z-aminomethano)prolinate 

Relevant academic research and scientific papers

An access to 3,4-(aminomethano)proline in racemic and enantiomerically pure form

Protected racemic and enantiomerically pure 3,4-(aminomethano)prolines rac-9 and (2S,2'R,3R,4R)-9 have been prepared applying a titanium-mediated reductive cyclopropanation as a key step. Thus, cyclopropanations of N,N-dibenzylformamide with titanacyclopr