87368-02-3Relevant academic research and scientific papers
Synthesis and transformations of metallacycles 28. Reactions of allenes with EtAlCl2 and Et2AlCl catalyzed by Ti and Zr complexes
Ibragimov,Khafizova,Gil'fanova,Dzhemilev
, p. 2255 - 2260 (2002)
Catalytic cycloalumination of allenes with EtAlCl2 in the presence of Ti or Zr complexes afforded methylidene- and alkyl(benzyl)idenealuminacyclopropanes and the corresponding aluminacyclopentanes, which were identified by analyzing the hydroly
Synthesis and transformations of metallacycles 35.* joint cycloalumination of cyclic 1,2-dienes with disubstituted acetylenes and terminal allenes under the action of EtAlCl 2 catalyzed by Ti and Zr complexes
D'yakonov,Timerkhanov,Tyumkina,Dzhemilev
, p. 2456 - 2464 (2014/05/06)
Catalytic intermolecular cycloalumination of cyclic 1,2-dienes with terminal allenes or disubstituted acetylenes mediated by EtAlCl2 in the presence of complexes based on transition metals was accomplished. The yield of unsaturated bicyclic alu
THE TITANOCENE METHYLENE-ZINC HALIDE COMPLEX: A CONVENIENT SYNTHESIS AND ITS METHYLENATING ACTION ON UNSATURATED CARBON CENTERS
Eisch, John J.,Piotrowski, Andrzej
, p. 2043 - 2046 (2007/10/02)
The titanocene methylene-zinc halide complex, which can be conveniently prepared by treating titanocene dichloride with methylenezinc iodide in THF solution, readily methylenates ketones, nitriles, and alkynes.
