87377-91-1Relevant academic research and scientific papers
Chiral 1,1′-binaphthylazepine derived amino alcohol catalyzed asymmetric Henry reaction
Guo, Zong-Liang,Zhong, Shi,Li, Yong-Bo,Lu, Gui
experimental part, p. 238 - 245 (2011/05/04)
The catalytic asymmetric Henry reaction of nitromethane to various aldehydes has been developed using a chiral binaphthylazepine derived amino alcohol and Cu(OAc)2·H2O as the catalyst. High yields and good enantioselectivities (up to
A highly diastereo-and enantioselective copper(I)-catalyzed henry reaction using a bis(sulfonamide)-diamine ligand
Jin, Wei,Li, Xincheng,Wan, Boshun
experimental part, p. 484 - 491 (2011/04/15)
A series of bis(sulfonamide)-diamine (BSDA) ligands were synthesized from commercially available chiral α-amino alcohols and diamines. The chiral BSDA ligand 3a, coordinated with Cu(I), catalyzes the enantioselective Henry reaction with excellent enantios
Method of producing organic compounds in presence of oxyethylene ether catalyst and in a solvent minimized environment
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Page 8-9, (2008/06/13)
A process of producing organic compounds, such as acetaminophen, nitroalcohols and indoles, employs a catalyst system of an oxyethylene ether and a metal containing inorganic or organic reagent. The oxyethylene ether at least partially complexes the metal of the inorganic or organic reagent. As such, the reactions may be conducted neat. The processes are environmentally friendly and operationally simple.
