87386-05-8

Basic information

• Product Name: ? (2-isocyanatophenyl)(phenyl)methanone
• Synonyms: ? (2-isocyanatophenyl)(phenyl)methanone
• CAS NO: 87386-05-8
• Molecular Weight: 223.231
• Mol File: 87386-05-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ? (2-isocyanatophenyl)(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: ? (2-isocyanatophenyl)(phenyl)methanone(87386-05-8)
• EPA Substance Registry System: ? (2-isocyanatophenyl)(phenyl)methanone(87386-05-8)

Safety Data

• Hazardous Substances Data: 87386-05-8(Hazardous Substances Data)

Upstream product

• 67862-73-1 (2-isothiocyanatophenyl)phenylmethanone 
• 33238-44-7 o-benzoylbenzoic acid azide 

Downstream Products

• 111838-36-9 4-ethoxy-4-phenyl-1,4-dihydro-3,1-benzoxazin-2(1H)-one 
• 7139-42-6 6,12-diphenyl-dibenzo[b,f][1,5]diazocine 

Relevant articles and documents

Sequential Oxidative Fragmentation and Skeletal Rearrangement of Peroxides for the Synthesis of Quinazolinone Derivatives

For the first time, the sequential reaction of peroxyoxindole that involves base-promoted oxidative fragmentation to isocyanate formation and primary amine or amino alcohol accelerated skeletal rearrangement to synthesize exo-olefinic-substituted quinazolinone or oxazoloquinazolinone is reported. The advantages of this new reaction include a broad substrate scope and transition-metal-free and room-temperature conditions. The formation of the isocyanate as a key intermediate that accelerates oxidative skeletal rearrangement has been confirmed by trapping experiments and spectroscopic evidence.

Isocyanate aus Isothiocyanaten durch Oxidation mit Palladium-chlorid und Luftsauerstoff

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