873876-62-1Relevant academic research and scientific papers
Atom-Economical Ni-Catalyzed Diborylative Cyclization of Enynes: Preparation of Unsymmetrical Diboronates
Cabrera-Lobera, Natalia,Quirós, M. Teresa,Brennessel, William W.,Neidig, Michael L.,Bu?uel, Elena,Cárdenas, Diego J.
, p. 6552 - 6556 (2019/08/20)
We report a Ni-catalyzed diborylative cyclization of enynes that affords carbo- and heterocycles containing both alkyl- and alkenylboronates. The reaction is fully atom-economical, shows a broad scope, and employs a powerful and inexpensive catalytic Ni-b
Iron-Catalyzed Hydroborylative Cyclization of 1,6-Enynes
Cabrera-Lobera, Natalia,Rodríguez-Salamanca, Patricia,Nieto-Carmona, Juan C.,Bu?uel, Elena,Cárdenas, Diego J.
, p. 784 - 788 (2017/11/29)
We report first Fe-catalyzed hydroborylative cyclization reaction. The process provides one C?C and one C?B bond in a single operation and shows a wide scope, allowing the formation of carbo- and heterocycles containing a homoallylic boryl unit that can b
Microwave-assisted rhodium-complex-catalyzed cascade decarbonylation and asymmetric Pauson-Khand-type cyclizations
Hang, Wai Lee,Lai, Na Lee,Chan, Albert S. C.,Fuk, Yee Kwong
supporting information; experimental part, p. 3403 - 3406 (2009/04/07)
Microwave-assisted Rh-diphosphane-complex-catalyzed dual catalysis is reported. This cooperative process provides [2+2+1] cycloadducts by sequential decarbonylation of aldehyde or formate and carbonylation of enynes within a short period of time. Various
Iridium-catalyzed cascade decarbonylation/highly enantioselective Pauson-Khand-type cyclization reactions
Kwong, Fuk Yee,Lee, Hang Wai,Lam, Wai Har,Qiu, Liqin,Chan, Albert S.C.
, p. 1238 - 1252 (2007/10/03)
An easily accessible chiral iridium-BINAP complex can effect the cooperative processes of decarbonylation of an aldehyde and cascaded enantioselective Pauson-Khand-type reaction. A survey of ligands revealed that atropisomeric aryl-diphosphine ligands wer
