87389-98-8

Basic information

• Product Name: (Z)-3-Amino-4-[2-(2-{2-[2-((Z)-2-amino-3-ethoxycarbonyl-allyloxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-but-2-enoic acid ethyl ester
• CAS NO: 87389-98-8
• Molecular Weight: 448.514
• Mol File: 87389-98-8.mol

Chemical Properties

• CAS DataBase Reference: (Z)-3-Amino-4-[2-(2-{2-[2-((Z)-2-amino-3-ethoxycarbonyl-allyloxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-but-2-enoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3-Amino-4-[2-(2-{2-[2-((Z)-2-amino-3-ethoxycarbonyl-allyloxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-but-2-enoic acid ethyl ester(87389-98-8)
• EPA Substance Registry System: (Z)-3-Amino-4-[2-(2-{2-[2-((Z)-2-amino-3-ethoxycarbonyl-allyloxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-but-2-enoic acid ethyl ester(87389-98-8)

Safety Data

• Hazardous Substances Data: 87389-98-8(Hazardous Substances Data)

Upstream product

• 87389-99-9 4-[2-(2-{2-[2-(3-Ethoxycarbonyl-2-oxo-propoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-3-oxo-butyric acid ethyl ester 

Relevant articles and documents

NICOTINIC ACID CROWN ETHERS: SYNTHESIS, COMPLEXATION AND REDUCTION

2,6-Bis(bromomethyl)nicotinic oxazoline (15), prepared from ethyl 2,6-dimethylnicotinate, was converted into the 1:1-macrocyclic oxazolines 19 and 22 as well as the isomeric macrocyclic dimers 20.Ethyl 2,6-bis(bromomethyl)nicotinate (23), prepared from 6b, was converted to the corresponding 1:1-dibenzo-18-crown-6 macrocyclic analog 24.NMR and mass spectral data were used to ascertain the macrocyclic structures.Reaction of 22 with EtMgBr afforded, after oxidation, the 4-substituted pyridino macrocycle 26 in high yield.However, under identical conditions, the non-oxazoline macrocycle 27 was recovered in toto.