873895-50-2Relevant academic research and scientific papers
Stereospecific synthesis of hetero[7]helicenes by Pd-catalyzed double N-arylation and intramolecular O-arylation
Nakano, Koji,Hidehira, Yuko,Takahashi, Keita,Hiyama, Tamejiro,Nozaki, Kyoko
, p. 7136 - 7138 (2007/10/03)
(Chemical Equation Presented) Enantioenriched aza- and oxa[7]helicenes are synthesized from an enantiopure biphenanthryldiol in a highly stereoselective manner. An N-phenylaza[7]helicene is prepared by a palladium-catalyzed double N-arylation of aniline w
