873932-93-5Relevant academic research and scientific papers
Gold and silver complexes with the ferrocenyl-pyrazolate ligand FcCH 2pz
Barranco, Eva M.,Gimeno, M. Concepción,Laguna, Antonio,Villacampa, M. Dolores
, p. 4177 - 4182 (2005)
We have synthesized a series of gold(I), gold(III) or silver(I) derivatives with ferrocenylmethylpyrazole (pzCH2Fc) as ligand. X-ray structure determination for [Au(C6F5)(pzCH2Fc)] reveals a linear geometry for the gold centre and association of the molecules in pairs through intermolecular gold(I)-gold(I) interactions of 3.1204(6) ?. These molecules are further assembled into chains and the chains into a 3D structure through several hydrogen bonds. [Ag(OTf)(pzCH2Fc)] (OTf = triflate) is a dimer with a distorted tetrahedral geometry at the silver(I) centre and the triflate acting as bridging ligand.
