87415-07-4Relevant academic research and scientific papers
SYNTHESIS OF ORTHO-SUBSTITUTED UNSATURATED ANILINES
Khusnitdinov, R. N.,Fakhretdinov, R. N.,Abdrakhmanov, I. B.,Panasenko, A. A.,Khalilov, L. M.,Dzhemilev, U. M.
, p. 920 - 924 (2007/10/02)
The Claisen rearrangement was investigated in the series of N-2,7-octadienylanilines under the influence of aqueous solutions of organic acids (CF3CO2H, CH3CO2H).It leads to unsaturated ortho-substituted anilines with yields of not less than 60percent.The highest yields of the respective unsaturated anilines (60-80percent) were obtained with trifluoroacetic acid as catalyst.
