874274-26-7

Basic information

• Product Name: [Ni(2-Me-PyNSO₂Ph-4-Me)(2,2'-bipyridine)]
• CAS NO: 874274-26-7
• Molecular Weight: 737.526
• Mol File: 874274-26-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ni(2-Me-PyNSO₂Ph-4-Me)(2,2'-bipyridine)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ni(2-Me-PyNSO₂Ph-4-Me)(2,2'-bipyridine)](874274-26-7)
• EPA Substance Registry System: [Ni(2-Me-PyNSO₂Ph-4-Me)(2,2'-bipyridine)](874274-26-7)

Safety Data

• Hazardous Substances Data: 874274-26-7(Hazardous Substances Data)

Upstream product

• 366-18-7 [2,2]bipyridinyl 
• 7440-02-0 nickel 

Relevant articles and documents

Electrochemical synthesis and characterization of nickel(II) complexes with N-2-pyridyl-sulfonamide ligands

Heteroleptic nickel(II) complexes [NiL2L′] of a series of monoanionic and potentially bidentate N-2-pyridyl-sulfonamide ligands [HL] and 2,2′-bipyridine or 1,10-phenanthroline (L′) have been prepared by electrochemical oxidation of a nickel anode in an acetonitrile solution of the ligands. The complexes have been characterized by microanalysis, IR and electronic spectroscopy, magnetic measurements and LSI mass spectrometry. The crystal structure of [Ni(Ms6mepy)2(bipy)] has been determined by x-ray diffraction and shows the metal in an octahedral NiN6 environment. Octahedral structures are also proposed for the other complexes with the N-2-pyridyl-sulfonamide ligands acting as N,N′ or N,O bidentate systems, depending on the position of the methyl substituent on the pyridine ring.