87437-11-4Relevant academic research and scientific papers
The 1,1-carboboration of bis(alkynyl)phosphanes as a route to phosphole compounds
Moebus, Juri,Bonnin, Quentin,Ueda, Kirika,Froehlich, Roland,Itami, Kenichiro,Kehr, Gerald,Erker, Gerhard
, p. 1954 - 1957 (2012)
Neat and tidy: B(C6F5)3 efficiently converts a series of bis(alkynyl)phosphanes into highly substituted 3-borylphospholes through a twofold 1,1-carboboration reaction sequence. The boron substituted phospholes were also used as substrates in Suzuki-Miyaura type cross-coupling reactions (see scheme).
Phosphine-catalysed reductive coupling of dihalophosphanes
Hering-Junghans, Christian,Schumann, André,Siewert, Jan-Erik
supporting information, p. 15111 - 15117 (2021/11/12)
Classically tetraaryl diphosphanes have been synthesized through Wurtz-type reductive coupling of halophosphanes R2PX or more recently, through the dehydrocoupling of phosphines R2PH. Catalytic variants of the dehydrocoupling reactio
Borata-alkene derivatives conveniently made by frustrated Lewis pair chemistry
Moebus, Juri,Kehr, Gerald,Daniliuc, Constantin G.,Froehlich, Roland,Erker, Gerhard
supporting information, p. 632 - 638 (2014/01/06)
Two (aryl)PXY starting materials (aryl = mesityl or 2,4,6- triisopropylphenyl; X,Y = Cl, Br) were reacted with lithiated conjugated enynes (derived from 2-methylbutenyne or 1-ethynylcyclohexene) to yield the respective (aryl)bis(enynyl)phosphanes. Their r
