87437-12-5Relevant academic research and scientific papers
2,6-diphospha-s-indacene-1,3,5,7(2H,6H)-tetraone: A phosphorus analogue of aromatic diimides with the minimal core exhibiting high electron-accepting ability
Takeda, Youhei,Nishida, Takuya,Minakata, Satoshi
supporting information, p. 10266 - 10270 (2014/08/18)
Phosphorus analogues of pyrromellitic diimides (PyDIs), which represent a family of privileged electron-accepting organic compounds, have been successfully synthesized as novel electron-accepting π-conjugated molecules. Investigation into their physicochemical properties uncovered their prominent electron-accepting abilities over the corresponding PyDI. Furthermore, theoretical studies revealed the significant contribution of σ*-π* hyperconjugation in stabilizing the LUMO+1.
The 1,1-carboboration of bis(alkynyl)phosphanes as a route to phosphole compounds
Moebus, Juri,Bonnin, Quentin,Ueda, Kirika,Froehlich, Roland,Itami, Kenichiro,Kehr, Gerald,Erker, Gerhard
supporting information; experimental part, p. 1954 - 1957 (2012/04/05)
Neat and tidy: B(C6F5)3 efficiently converts a series of bis(alkynyl)phosphanes into highly substituted 3-borylphospholes through a twofold 1,1-carboboration reaction sequence. The boron substituted phospholes were also used as substrates in Suzuki-Miyaura type cross-coupling reactions (see scheme).
