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Usage

Physical state

Colorless liquid 2,6-dithiaspiro[3.3]heptane 2,6-dioxide is a liquid that is colorless in appearance.

Usage

Solvent and synthesis of organic compounds 2,6-dithiaspiro[3.3]heptane 2,6-dioxide is used as a solvent for various chemical reactions and as a starting material for the synthesis of other organic compounds.

Unique structure

Spirocyclic with two sulfur atoms and a six-membered ring The compound has a distinctive structure that includes a six-membered ring and two sulfur atoms, which contributes to its unique properties and applications.

Applications

Production of pharmaceuticals and agrochemicals Due to its unique chemical properties, 2,6-dithiaspiro[3.3]heptane 2,6-dioxide is used in the manufacturing of pharmaceuticals and agrochemicals.

Potential applications

Various industries The compound's unique chemical properties and structure make it suitable for use in a wide range of industries, offering potential for further development and utilization.

Upstream product

• 174-81-2 2,2'-dithiaspiro<3,3>heptane 

Relevant academic research and scientific papers

Design of a new axially chiral molecule by conformational fixation: 2,6-dithiaspiro[3.3]heptane 2,6-dioxide and its heavier analogues

We have designed a new axially chiral bis(sulfoxide) molecule with conformational rigidity: 2,6-dithiaspiro[3.3]heptane 2,6-dioxide 2a. This molecule has axial asymmetry due to two puckered thietane ring systems. The lone pairs on the sulfur show a strong s-character, which was expected to result in a high barrier to racemization, that is, inversion at the sulfur. We confirmed this prediction by calculations and experimentation. The lone pairs of the sulfur in 2a are sp1.00 and the enthalpy of activation (ΔH ?) for inversion is 47.5 kcal/mol (B3LYP/6-31G(d)). The 1H NMR spectra of 2a showed two doublets and two doubled doublet peaks, which resulted from the rigidity of the four-membered ring frameworks without flipping. We separated the enantiomers of 2a by HPLC with a chiral stationary phase column to observe a set of complementary peaks. We also calculated the diselena- and ditellura congeners and confirmed that they also show axial chirality.

ULTRA LONG-RANGE THROUGH-BOND INTERACTIONS IN DITHIASPIRANE DISULFOXIDES AS REVEALED BY PHOTOELECTRON SPECTROSCOPY

Ultraviolet photoelectron spectra of the disulfoxides of 2,6-dithiaspiro heptane, 2,8-dithiaspiro decane, and 2,10-dithiaspiro tridecane show that there are substantial trough-bond interactions of the sulfur lone-pairs, ran