87448-32-6Relevant academic research and scientific papers
Chiral Induction in the Addition of the Anion from 3-(p-Methylbenzenesulfinyl)prop-1-ene with Substituted Benzaldehydes
Ridley, Damon D.,Smal, Mary A.
, p. 1049 - 1055 (2007/10/02)
Addition of the anion from 3-(p-methylbenzylsulfinyl)prop-1-ene to substituted benzaldehydes affords mixtures os α- and γ-products.The diastereoisomeric ratios, which were determined by 1H n.m.r. spectroscopy, appeared independent of electronic factors.Possible transition state models to account for the stereochemical aspects of the reaction are discussed.
