874655-60-4Relevant academic research and scientific papers
One-pot tandem 1,4-1,2-addition of phosphites to α,β-unsaturated imines for the synthesis of glutamic acid analogues
Moonen, Kristof,Van Meenen, Ellen,Verwee, Annelies,Stevens, Christian V.
, p. 7407 - 7411 (2005)
(Chemical Equation Presented) Evidently so: New mechanistic findings indicate that addition of dialkyl trimethylsilyl phosphites to α,β-unsaturated imines has been incorrectly reported as an exclusive 1,2-addition. When α,β-unsaturated imines are used as
Tandem addition of trialkyl phosphites to α,β-unsaturated imines: A comparison with silylated phosphites
Van Meenen, Ellen,Moonen, Kristof,Verwee, Annelies,Stevens, Christian V.
, p. 7903 - 7906 (2007/10/03)
(Chemical Equation Presented) Trialkyl phosphites were evaluated for addition reactions to α,β-unsaturated imines. An acidic medium is required to allow consecutive 1,4- and 1,2-addition to occur. In this manner, 3-phosphonyl-1-aminophosphonates, phosphon
