874758-24-4

Basic information

• Product Name: 2,3-diethynyl-1-trideuteriomethoxybenzene
• Synonyms: 2,3-diethynyl-1-trideuteriomethoxybenzene
• CAS NO: 874758-24-4
• Molecular Weight: 159.16
• Mol File: 874758-24-4.mol

Chemical Properties

• CAS DataBase Reference: 2,3-diethynyl-1-trideuteriomethoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-diethynyl-1-trideuteriomethoxybenzene(874758-24-4)
• EPA Substance Registry System: 2,3-diethynyl-1-trideuteriomethoxybenzene(874758-24-4)

Safety Data

• Hazardous Substances Data: 874758-24-4(Hazardous Substances Data)

Upstream product

• 874758-28-8 2,3-diiodo-3-trideuteriomethoxybenzene 
• 874758-26-6 2-iodo-1-trideuteriomethoxy-3-nitrobenzene 
• 874758-27-7 2-iodo-3-trideuteriomethoxy-1-aminobenzene 
• 874758-29-9 2,3-bis(trimethylsilylethynyl)-1-trideuteriomethoxybenzene 

Downstream Products

• 77746-29-3 1-[α,α,α-2H3]-methoxynaphthalene 

Relevant articles and documents

Ortho effect in the Bergman cyclization: Interception of p-benzyne intermediate by intramolecular hydrogen abstraction

Intramolecular hydrogen atom (H-atom) abstraction from the o-OCH 3 group effectively intercepts the p-benzyne intermediate in the Bergman cycloaromatization of 2,3-diethynyl-1-methoxybenzene (1) before this intermediate undergoes either retro-Bergman ring opening or external H-atom abstraction. This process leads to the formation of a new diradical and renders the cyclization step essentially irreversible. Chemical and kinetic consequences of this phenomenon were investigated through the combination of computational and experimental studies.