87480-43-1 Usage
Chemical class
Polycyclic aromatic hydrocarbon (PAH)
Explanation
This compound is composed of multiple fused aromatic rings, which are characteristic of PAHs.
Explanation
The chemical structure consists of a large number of carbon and hydrogen atoms arranged in a complex, condensed pattern.
Explanation
The molecule has several stereocenters (alpha, beta, etc.), which indicate the presence of different spatial arrangements of atoms.
Explanation
The compound contains aromatic rings, which are characterized by their stability and delocalized electron systems.
Explanation
The molecule has undergone hydrogenation, which means it has twelve hydrogen atoms added to its structure, making it a dodecahydro derivative.
Explanation
The presence of stereocenters (alpha, beta, etc.) indicates that the molecule has chiral centers, which can lead to different enantiomers or diastereomers.
Explanation
This complex organic compound is primarily used in scientific research, likely due to its unique structure and potential for studying chemical reactions and properties.
Explanation
As a complex hydrocarbon, it is expected to be poorly soluble in water but may have better solubility in organic solvents like hexane or toluene.
Explanation
The complex structure of the molecule suggests that it may undergo a range of chemical reactions, such as electrophilic aromatic substitution, oxidation, or reduction, depending on the specific functional groups and reaction conditions.
Explanation
Due to its complex structure and classification as a PAH, this compound may have unknown hazards and should be handled with care in a laboratory setting.
Explanation
This compound is not typically found in the environment and is primarily used in scientific research, so its occurrence in everyday life is minimal.
Molecular structure
Highly condensed and complex
Stereochemistry
Contains multiple stereocenters
Hydrocarbon type
Aromatic hydrocarbon
Hydrogenation
Dodecahydro
Chirality
Contains chiral centers
Application
Scientific research
Solubility
Likely insoluble in water
Stability
Relatively stable under normal conditions
Reactivity
Potential for various chemical reactions
Hazards
Unknown, but potentially hazardous
Environmental occurrence
Not commonly encountered
Check Digit Verification of cas no
The CAS Registry Mumber 87480-43-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,7,4,8 and 0 respectively; the second part has 2 digits, 4 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 87480-43:
(7*8)+(6*7)+(5*4)+(4*8)+(3*0)+(2*4)+(1*3)=161
161 % 10 = 1
So 87480-43-1 is a valid CAS Registry Number.
InChI:InChI=1/C17H22/c1-2-9-5-8(1)14-12-7-13(15(9)14)17-11-4-3-10(6-11)16(12)17/h1-2,8-17H,3-7H2
87480-43-1Relevant articles and documents
Crystal Structures and Photoelectron Spectra of Some Trimethanoanthracenes, Tetramethanonaphthacenes, and Pentamethanopentacenes. Experimental Evidence for Laticyclic Hyperconjugation
Paddon-Row, Michael N.,Englehardt, Lutz M.,Skelton, Brian W.,White, Allan H.,Joergensen, Flemming S.,Patney, Harish K.
, p. 1835 - 1850 (2007/10/02)
Photoelectron (p.e.) spectra of the series of dienes (4), (10), (11a)-(13a), and crystal structures for the dodecachlorodienes (11b)-(13b) are reported.The spectra revealed large ?-splitting energies of 0.32 and 0.52 eV for (4) and (11a) respectively.The value of (4) is attributed to the presence of orbital interactions through six ? bonds (OIT-6-B), and this, taken with the p.e. data for the dienes (1)-(3), provides convincing evidence for the long-range nature of OIT-n-B.The larger ?-splitting energy of 0.52 eV observed for (11a), compared with (4), has been explained in terms of the presence of two reinforcing orbital interactions: OIT-6-B and a new variant of hyperconjugation, called laticyclic hyperconjugation, in which the ? MOs of the double bonds mix the (Ψ)? MO of the central CH2 bridge of (11a).The surprisingly large ?-splitting energy of 0.29 eV observed for (12a) is also due largely to laticyclic hyperconjugation involving both pairs of symmetry adapted(Ψ)? MOs of the CH2 bridges.No ?-splitting energy could be detected in the p.e. spectrum of (13a).From the crystal structures of (11b)-(13b), it was found that the distance between neighbouring CH2 groups, and between a double bond and its closest CH2 neighbour is about 3 Angstroem in all three compounds.HF/STO-3G calculations on model ethene...(CH4)n...ethene complexes suggest that laticyclic interactions, like OIT-n-B, are very long-range processes, the predicted ?-splitting energies amounting to ca. 10-3 eV for two double bonds separated by ca. 33 Angstroem.The relevance of these orbital interactions to biological electron-transfer processes is briefly discussed.
Diels-Alder-Reactions. VIII. Kinetic Investigations of the Formation and the Pyrolysis of Tetracyclo3.6.02.7>dodec-4-en
Moll, K. K.,Ramhold, K.,Zimmermann, G.,Pohle, Ch.
, p. 1048 - 1052 (2007/10/02)
The formation of tetracyclo3.6.02.7>dodec-4-ene by codimerisation of cyclopentadiene with bicyclohept-2-ene between 60 and 140 deg C in the liquid phase and the inverse reaction by gas phase pyrolysis between 240 and 300 deg C were studied kinetically.The activation parameters were determined.
