87481-60-5Relevant academic research and scientific papers
Synthesis of Thione S-Imides by Alkylidenation of Sulfinylanilines and Imination of Sulfines
Porskamp, Pascal A. T. W.,Zwanenburg, Binne
, p. 4582 - 4585 (2007/10/02)
Thione S-imides 3 have been synthesized by alkylidenation of sulfinylamines 1 using α-trimethylsilyl carbanions 2.Imination of sulfines 4 by means of anions of (trimethylsilyl)amines 5 also led to thione S-imides 3.It was found to be essential that in these syntheses the thione S-imides are substituted with sterically filled groups.
