874892-54-3Relevant academic research and scientific papers
Titanium complexes supported by a sterically encumbering N-anchored tris-arylphenoxide ligand
Cortes, Sara A.,Mu?oz Hernández, Miguel A.,Nakai, Hidetaka,Castro-Rodriguez, Ingrid,Meyer, Karsten,Fout, Alison R.,Miller, Deanna L.,Huffman, John C.,Mindiola, Daniel J.
, p. 903 - 907 (2005)
A family of neutral and cationic Ti(IV) complexes supported by the sterically demanding and trianionic ligand (O3N)3- (O 3N3- = tris(2-O,3-Ad,5-tBubenzyl)amine, Ad = 1-adamantyl) have been prepared from the hydrolysis of TiCl4(THF)2 with the free base (O3N)H3 and excess NEt3, followed by anion exchange reactions. These (O3N)Ti+ cores are resistant to moisture and air, are mononuclear, and possess C3 symmetry on the NMR timescale.
