87498-96-2Relevant academic research and scientific papers
Coordination Compounds of Organometallic Bases of Group IV Elements: Part III - Unusual Reactions of Benzylamino/n-butylamino-triethoxy/triphenoxy-silanes with Antimony(III) Halides
Narula, Suraj P.,Kapur, Neeta
, p. 557 - 559 (2007/10/02)
Benzylamino/n-butylamino-triethoxy/triphenoxy-silanes and SbX3 (X = Cl, Br) in chloroform at 0 deg C and SbI3 in carbon tetrachloride at room temperature, react to give solid adducts of compositions ROSi(NHR)3.nSbX3 (n = 1 or 2) and (C2H5O)2Si(NHC4H9)2.2SbCl3.The structure of these complexes has been established by elemental analyses, infrared and PMR spectroscopy.The bases are proposed to undergo disproportionation in these reactions.
