87511-39-5

Basic information

• Product Name: [PtH(P(C(CH₃)3)2CH₂CH(CH₃)CH₂)(P(C₆H₅)3)]
• CAS NO: 87511-39-5
• Molecular Weight: 659.691
• Mol File: 87511-39-5.mol

Chemical Properties

• CAS DataBase Reference: [PtH(P(C(CH₃)3)2CH₂CH(CH₃)CH₂)(P(C₆H₅)3)](CAS DataBase Reference)
• NIST Chemistry Reference: [PtH(P(C(CH₃)3)2CH₂CH(CH₃)CH₂)(P(C₆H₅)3)](87511-39-5)
• EPA Substance Registry System: [PtH(P(C(CH₃)3)2CH₂CH(CH₃)CH₂)(P(C₆H₅)3)](87511-39-5)

Safety Data

• Hazardous Substances Data: 87511-39-5(Hazardous Substances Data)

Upstream product

• 16940-66-2 sodium tetrahydroborate 
• 87511-37-3 [PtCl(P(C(CH₃)3)2CH₂CH(CH₃)CH₂)(P(C₆H₅)3)] 

Relevant articles and documents

TRANSITION METAL-CARBON BONDS. LV. CYCLOMETALLATION AND OTHER REACTIONS OF PBut2Bui AND PPh2Bui WITH PLATINUM(II) AND PALLADIUM(II)

The new phosphine, PBut2Bui (L), was prepared from But2PCl and LiBui.PPh2Bui (L') was prepared from PH2PCl and LiBui.Treatment of t)2> with L' gives which does not cyclometallate even on prolonged boiling in 2-methoxyethanol.In contrast, t)2> reacts with PBut2Bui in boiling 2-methoxyethanol to give the cyclometallated complex (II, X = Cl).The corresponding bromide, iodide and acetylacetonate were prepared.With PPh3 II (X = Cl) gives which with NaBH4 gives .Na2PdCl4 with L (2 mol equivalents) gave trans-, which was converted into trans- by metathesis with KSCN.Treatment of Na2PdCl4 with L (1 mol equivalent) gave , which on heating in 2-methoxyethanol gave , as a mixture of syn- and anti-isomers.The complexes trans- and were also prepared. 1H- and 31P NMR data are given.