87514-04-3

Basic information

• Product Name: (E)-1-phenylsulfanyl-1-trimethylsilyl-1-octene
• Synonyms: (E)-1-phenylsulfanyl-1-trimethylsilyl-1-octene
• CAS NO: 87514-04-3
• Molecular Weight: 292.561
• Mol File: 87514-04-3.mol

Chemical Properties

• CAS DataBase Reference: (E)-1-phenylsulfanyl-1-trimethylsilyl-1-octene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-phenylsulfanyl-1-trimethylsilyl-1-octene(87514-04-3)
• EPA Substance Registry System: (E)-1-phenylsulfanyl-1-trimethylsilyl-1-octene(87514-04-3)

Safety Data

• Hazardous Substances Data: 87514-04-3(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 101653-64-9 (E)-1-iodo-1-(trimethylsilyl)-1-octene 
• 15719-55-8 trimethyl(oct-1-yn-1-yl)silane 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 75717-40-7 (E)-oct-1-enylsulfanyl-benzene 

Relevant articles and documents

A facile stereoselective synthesis of (E)-α-silylyinyl sulfides via hydromagnesiation of alkynylsilanes

Hydromagnesiation of alkynylsilanes 1 in diethyl ether gave (Z)-α-silylvinyl Grignard reagents 2, which reacted with arylsulfenyl chlorides 3 to afford stereoselectively (E)-α-silylvinyl sulfides 4 in good yields. (E)-α-Silylvinyl sulfides 4 could undergo

Stereo-recognizing transformation of (E)-alkenyl halides into sulfides catalyzed by nickel(0) triethyl phosphite complex

(E)-Alkenyl halides were transformed into (E)-alkenyl sulfides by the nickel(0) triethyl phosphite complex-catalyzed reaction with thiols, whereas (Z)-alkenyl halides gave alkynes under the same reaction conditions. Aryl halides were also transformed into aryl sulfides using the same reagent system.