87514-09-8

Basic information

• Product Name: (+/-)-2-phenylthio-2-cyclohexenol
• Synonyms: (+/-)-2-phenylthio-2-cyclohexenol
• CAS NO: 87514-09-8
• Molecular Weight: 206.309
• Mol File: 87514-09-8.mol

Chemical Properties

• CAS DataBase Reference: (+/-)-2-phenylthio-2-cyclohexenol(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-2-phenylthio-2-cyclohexenol(87514-09-8)
• EPA Substance Registry System: (+/-)-2-phenylthio-2-cyclohexenol(87514-09-8)

Safety Data

• Hazardous Substances Data: 87514-09-8(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 143100-78-1 (1α,2β,6β)-1-(trimethylsilyl)-7-oxabicyclo<4.1.0.>heptan-2-ol 
• 87514-07-6 (E)-6-Phenylsulfanyl-6-trimethylsilanyl-hex-5-enal 
• 23740-61-6 2-(phenylsulfanyl)-2-cyclohexanone 

Downstream Products

• 157239-37-7 (-)-2-phenylthiocyclohex-2-ene-1-ol 
• 396728-98-6 (+/-)-2-(phenylsulfonyl)-2-cyclohexen-1-ol 
• 7472-23-3 2-benzoyloxycyclohexanone 

Relevant articles and documents

Nucleophilic epoxidation of α′-hydroxy vinyl sulfoxides

The nucleophilic epoxidation of a variety of α′-(1-hydroxyalkyl) vinyl sulfones and sulfoxides has been studied. The sulfones give rise to anti oxiranes with modest (E) or excellent (Z) selectivities and in good yields. The (E)-sulfoxides display low reactivity within a reinforcing/nonreinforcing scenario. The use of t-BuOOLi in Et2O allows for a highly syn-selective epoxidation-oxidation. The (Z)-sulfoxides display a remarkably high reactivity under these conditions. The reinforcing (S,Ss) diastereomers (3e-g) yield hydroxy sulfinyl oxiranes with high yields and selectivities. In contrast, the (R,Ss) diastereomers (4e-g) show diminished reactivities and a very substrate-dependent stereochemical outcome. The structure of these oxiranes has been secured by chemical correlations and an X-ray crystal structure.

Stereochemically defined cyclohexanediols through the regioselective ring-opening of silylated epoxy alcohols

The nucleophilic ring-opening of the silylated epoxy alcohol 2 leads to highly functionalized building blocks of defined stereochemistry, whereby the regioselectivity may be controlled through the proper choice of the nucleophilic and the reaction conditi

Reactions of 2-phenylthio-2-cycloalkenones and 2-[phenyl(thiomethyl)]-2-cycloalkenones. Synthesis of some useful chiral and achiral intermediates

The allyl acetates derived from 2-phenylthio-2-cyclopentenone, 2-phenylthio-2-cyclohexenone, 2-[phenylthio(methyl)]-2-cyclopentenone and 2-[phenylthio(methyl)]-2-cyclohexenone have been hydrolysed by pig liver acetone powder to obtain the corresponding al

Enantiocomplementary resolution of 2-phenylthio-2-cyclopentenol and 2-phenylthio-2-cyclohexenol using the same lipase

Both racemic 2-phenylthio-2-cyclopentenol (±)-(3a) and 2-phenylthio-2-cyclohexenol (±)-(3b) afford the corresponding (R)-acetates (R)-4a,b and the unreacted (S)-alcohols (S)-3a,b, respectively, in excellent optical and chemical yields on treatment with vi

CLEAVAGE OF SILICON-VINYL CARBON BOND BY nBu4NF

Dimethylphenylsilyl- and diphenylmethylsilyl-vinyl carbon bonds are cleaved with nBu4NF.Desilylation of 1-phenylthio-1-trimethylsilyl-1-alkenes in the presence of aldehyde moiety gives carbanion adducts.