875167-72-9Relevant academic research and scientific papers
Synthesis of diphenylphosphine oxide and diethyl phosphonate with 4-dimethylsila-2-hexen-6-ol moiety
Gawdzik,Wawrzenczyk
, p. 541 - 545 (2007/10/03)
Two reagents useful for the Horner-Wittig or Wadshworth-Emmons reaction: 3-(2-hydroxyethyldimethylsila)-2-propen-1-yldiphenylphosphine oxide (5a) and diethyl 3-(2-hydroxyethyldimethylsila)-2-propen-1-ylphosphonate (5b) were synthesized from propargyl chloride and dimethylchlorosilane. The usefulness of phosphine oxide was demonstrated in the olefmation reactions of benzaldehyde and hexanal.
