875212-80-9Relevant academic research and scientific papers
The first enzymatic resolution of quaternary α′-acetoxy α,β-unsaturated cyclohexenones and cyclopentenones
Tanyeli, Cihangir,Oezdemirhan, Fazilet Devrim,Iyiguen, Cigdem
, p. 4050 - 4055 (2005)
The enantioselective resolution of various quaternary α′- acetoxy α,β-unsaturated cyclohexenones and cyclopentenones was performed with the commercially available enzyme CCL in pH = 8.0 phosphate buffer. Various parameters that would affect the enantiosel
Manganese(III) acetate based oxidation of substituted α′-position on cyclic α,β-unsaturated ketones
Tanyeli, Cihangir,Iyigün, ?igdem
, p. 7135 - 7139 (2007/10/03)
Selective oxidation of the tertiary α′-position on various 2-cyclopentenone, 2-cyclohexenone and aromatic ketone derivatives with manganese(III) acetate is described.
Manganese(III) acetate based selective oxidation of the tertiary α′-position on various cyclic α,β-unsaturated ketones
Tanyeli, Cihangir,Sezen, Bengü,Iyigün, ?igdem,Elmal, Olcay
, p. 6397 - 6399 (2007/10/03)
We describe the preliminary results of manganese(III) acetate based selective oxidation of various α′-methyl 2-cyclohexenone and 2-cyclopentenone derivatives to afford the corresponding α′-acetoxy-α′-methyl substituted oxidation products in good yields.
