875295-80-0Relevant academic research and scientific papers
Structure and magnetic properties of a low-spin manganese(III) phthalocyanine dicyanide complex
Matsuda, Masaki,Yamaura, Jun-Ichi,Tajima, Hiroyuki,Inabe, Tamotsu
, p. 1524 - 1525 (2005)
A manganese(III) complex salt, TPP[MnIII(Pc)(CN) 2]· DCM was crystallized in dichloromethane solution (Pc = phthalocyaninato, TPP+ = tetraphenylphosphonium, and DCM = dichloromethane). In the crystal, Pc molecules form a pair of one-dimensional regular chains along the c axis. The magnetic susceptibility measurement revealed Mn ions in the low-spin state (S = 1) and a spin-orbit coupling effect due to the incomplete quenching of the angular orbital moment under the symmetrical ligand field. Copyright
