87532-90-9Relevant academic research and scientific papers
Insertion of zerovalent metals into the C-N bonds of N,N′-bridged porphyrins
Chan, Yee Wei,Renner, Mark W.,Balch, Alan L.
, p. 1888 - 1889 (2008/10/08)
Treatment of the N,N′-bridged tetraphenylporphyrin (TPPC=C(p-ClC6H4)2) with Fe3(CO)12 or Ru3(CO)12 yields the metallocarbene complexes TPPM{C=C(p-C6H4Cl)2} in which both N-C bonds are broken, while a similar reaction with Ni(CO)4 yields TPP{C=C(p-C6H4Cl)2}Ni in which only one N-C bond is broken.
