875325-74-9Relevant academic research and scientific papers
Cobalt-salen complex-catalyzed oxidative generation of alkyl radicals from aldehydes for the preparation of hydroperoxides
Watanabe, Eiichi,Kaiho, Atsushi,Kusama, Hiroyuki,Iwasawa, Nobuharu
supporting information, p. 11744 - 11747 (2013/09/02)
Catalytic generation of alkyl radicals from aldehydes via oxidative deformylation was realized using a cobalt-salen complex with H2O 2. The deformylation was thought to proceed through homolytic cleavage of peroxohemiacetal intermediates to provide even primary alkyl radicals under mild conditions. Variously substituted and functionalized hydroperoxides were obtained from corresponding aldehydes in good yield.
Novel synthesis of substituted cyclopropane acetic acid ethyl esters from cyclopropyl alkyl ketones
Nongkhlaw, Rishan Lang,Nongrum, Ridaphun,Nongkynrih, Irona,Vattakunnel, Felix Mathew,Myrboh, Bekington
, p. 1054 - 1057 (2007/10/03)
The cyclopropane acetic acid ethyl esters 2 have been conveniently prepared in one step from cyclopropyl alkyl ketones 1 by reacting with lead (IV) acetate in triethyl orthoformate in the presence of 70% perchloric acid. In all these reactions triethyl or
