87534-03-0

Basic information

• Product Name: 9,32-di-O-(4-iodobenzoyl)-O-β-D-kijanosyl-(1->17)-kijanolide
• CAS NO: 87534-03-0
• Molecular Weight: 1242.94
• Mol File: 87534-03-0.mol

Chemical Properties

• CAS DataBase Reference: 9,32-di-O-(4-iodobenzoyl)-O-β-D-kijanosyl-(1->17)-kijanolide(CAS DataBase Reference)
• NIST Chemistry Reference: 9,32-di-O-(4-iodobenzoyl)-O-β-D-kijanosyl-(1->17)-kijanolide(87534-03-0)
• EPA Substance Registry System: 9,32-di-O-(4-iodobenzoyl)-O-β-D-kijanosyl-(1->17)-kijanolide(87534-03-0)

Safety Data

• Hazardous Substances Data: 87534-03-0(Hazardous Substances Data)

Upstream product

• 78798-21-7 O-β-D-kijanosyl-(1->17)-kijanolide 
• 1711-02-0 4-iodobenzoic acid chloride 

Downstream Products

• 87534-04-1 9,32-di-O-(4-iodobenzoyl)-O-β-D-kijanosyl-(1->17)-26-O-methylkijanolide 

Relevant articles and documents

Kijanimicin. Part 3. Structure and Absolute Stereochemistry of Kijanimicin

Kijanimicin, a novel antibiotic from Actinomadura kijaniata nov. sp.SCC1256 (ATCC 31588), has been shown by chemical degradation, spectroscopic studies, and X-ray crystallographic studies to have a unique tetronic acid structure.The molecule contains a branched chain tetrasaccharide moiety consisting of three units of 2,6-dideoxy-α-L-ribo-hexopyranose and one unit of 2,6-dideoxy-4-O-methyl-β-L-ribo-hexopyranose.The molecule also contains a novel nitrosugar, namely 2,3,4,6-tetradeoxy-4-methoxycarbonylamino-3-C-methyl-3-nitro-β-D-xylo-hexopyranose (D-kijanose), which is the third nitrosugar to be isolated from an antibiotic.The structure of L-rubranitrose is revised to D-rubranitrose.Evidence for the total structure, the absolute stereochemistry, and the solution conformation of kijanimicin is presented.