875539-28-9Relevant academic research and scientific papers
A stable hydrido amido ruthenium complex bearing a tridentate iminophosphorane-phosphine-amine ligand
Boubekeur, Leila,Ulmer, Simon,Ricard, Louis,Mezailles, Nicolas,Floch, Pascal Le
, p. 315 - 317 (2006)
A heterotrideniate (P,N,N′) ligand featuring phosphine, iminophosphorane, and amine groups has been prepared in high yield. The corresponding dichlororuthenium(II) complex reacts with base in 2-propanol to give a stable hydrido amido complex. The lack of hydrogens that are a to the amine allowed for the isolation and structural characterization of this hydrido amido species by X-ray diffraction.
