87567-39-3

Basic information

• Product Name: [2-(2-Cyclopentylidene-ethanesulfonyl)-1,1-dimethyl-ethyl]-benzene
• CAS NO: 87567-39-3
• Molecular Weight: 292.442
• Mol File: 87567-39-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [2-(2-Cyclopentylidene-ethanesulfonyl)-1,1-dimethyl-ethyl]-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [2-(2-Cyclopentylidene-ethanesulfonyl)-1,1-dimethyl-ethyl]-benzene(87567-39-3)
• EPA Substance Registry System: [2-(2-Cyclopentylidene-ethanesulfonyl)-1,1-dimethyl-ethyl]-benzene(87567-39-3)

Safety Data

• Hazardous Substances Data: 87567-39-3(Hazardous Substances Data)

Upstream product

• 3859-35-6 1-vinyl-1-cyclopentanol 
• 28638-58-6 1-vinylcyclopentene 
• 67686-36-6 Sodium Neophylsulfinate 

Relevant articles and documents

Regio- and Stereoselective Hydrosulfonylation of Conjugated Dienes via a (?-Allyl)palladium Complex

The combination of a sulfonylpalladation of acyclic dienes 1 (with 2 equiv of NaSO2R and 1 equiv of PdCl2 in acetic acid or acetic acid-H2O at 50-80 deg C under air) and a protiodepalladation of the thus obtained palladium complexes 3 with dimethylglyoxime (in a protic solvent at room temperature) provides di- and trisubstituted (Z)-Δ3-sulfones 12 selectively, irrespective of the stereochemistry of the starting dienes.Similar treatment of 1-vinylcycloalkenes 5 (n (1,3) strain between Pd and the substituent on the allylic position.