87573-96-4Relevant articles and documents
“Metal-free” electrooxidative C—H thiocyanation of arenes
Kokorekin,Mel’nikova,Yaubasarova,Gorpinchenko,Petrosyan
, p. 2140 - 2141 (2020/01/21)
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Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles
Kuhn, Bruna L.,Fortes, Margiani P.,Kaufman, Teodoro S.,Silveira, Claudio C.
, p. 1648 - 1652 (2014/03/21)
A concise, two-step eco-friendly approach towards the synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles, is reported. The synthesis comprises the oxone-mediated thiocyanation of the starting heterocycles towards intermediate 3-thiocyanato indoles and 2-thiocyanato pyrroles, and their subsequent treatment with sodium azide in 2-propanol/water under zinc bromide promotion.
New data on heteroarene thiocyanation by anodic oxidation of NH 4SCN. the processes of electroinduced nucleophilic aromatic substitution of hydrogen
Kokorekin, Vladimir A.,Sigacheva, Vera L.,Petrosyan, Vladimir A.
supporting information, p. 4306 - 4309 (2014/07/22)
Potentiostatic (galvanostatic) electrolysis of NH4SCN in an undivided cell under mild conditions (25 °C, Pt anode, MeCN) was employed to perform the anodic thiocyanation of nitrogen-containing heterocycles with yields up to 95%. The regularitie