87575-33-5Relevant academic research and scientific papers
ELECTROCHEMICAL PROCEDURE DIRECTED TO THE SELECTIVE RING OPENING OF EPOXIDES TO ALLYLIC ALCOHOLS
Uneyama, Kenji,Nisiyama, Noriyuki,Torii, Sigeru
, p. 4137 - 4138 (2007/10/02)
A transformation of epoxides 2 into allylic alcohols 1 was achieved by an electrogenerated acid-catalysis in ClCH2CH2Cl - TsONa - TsONEt4 - Pt system.
ELECTROGENERATED ACID AS A POWERFUL CATALYST FOR TRANSFORMATION OF EPOXIDES TO KETONES AND ACETONIDES
Uneyama, Kenji,Isimura, Akihiro,Fujii, Kazuyuki,Torii, Sigeru
, p. 2857 - 2860 (2007/10/02)
Electrochemical Transformation of epoxides 1 to ketones 2 and acetonides 3 were achieved by using an electrogenerated acid-catalyst.A combination of M(ClO4)n with polar aprotic solvents is useful for the electrochemical transformation.
