875757-96-3Relevant articles and documents
Synthesis of the bicyclo[3.3.1]nonane core of huperzine a and novel pyridine-fused tricycles by cyclisation of pyridine-based radicals
Ward, Jarrod,Caprio, Vittorio
experimental part, p. 791 - 804 (2009/12/01)
The cyclisation of 3-pyridyl radicals and (2-pyridyl)methyl radicals, generated from (pyridyl)cyclohexenols 5 to 8, has been examined as part of a model study directed towards the synthesis of huperzine A. The 3-pyridyl radical, generated from 3-bromopyri
A radical mediated approach to the core structure of huperzine A
Ward, Jarrod,Caprio, Vittorio
, p. 553 - 556 (2007/10/03)
The synthesis of the core structure of huperzine A by cyclisation of 2-pyridylmethyl radicals is described. (2-Methylpyridin-3-yl)cyclohexenols are directly selenated at the benzylic position by deprotonation/selenation and the products undergo either 5-e
