875768-16-4Relevant articles and documents
Gold-catalyzed stereoselective synthesis of azacyclic compounds through a redox/[2 + 2 + 1] cycloaddition cascade of nitroalkyne substrates
Jadhav, Appaso Mahadev,Bhunia, Sabyasachi,Liao, Hsin-Yi,Liu, Rai-Shung
supporting information; experimental part, p. 1769 - 1771 (2011/04/15)
We report a new redox/cycloaddition cascade on readily available 1-alkynyl-2-nitrobenzenes that produces complex azacyclic compounds stereoselectively. The core structures of the resulting products are constructed through a formal [2 + 2 + 1] cycloaddition among α-carbonyl carbenoids, nitroso species, and external alkenes.