875829-29-1Relevant academic research and scientific papers
Stereospecific Synthesis of Diastereoisomerically Pure (-)-(RP)-O-Mentyl Methylphenylphosphinite and Ethylphenylphosphinite: Key Intermediates in Synthesis of Chiral Tertiary Phosphines
Omelanczuk, Jan,Perlikowska, Wieslawa,Mikolajczyk, Marian
, p. 24 - 25 (2007/10/02)
The reaction of the diastereoisomerically pure (-)-(RP)-O-mentyl methylphenylphosphinite (9) and (-)-(RP)-O-mentyl ethylphenylphosphinite (2) with organolithium reagents has been found to give chiral tertiary phosphines (10) and (11) with a very high optical purity.
