87591-37-5Relevant academic research and scientific papers
Esterase catalyzed regioselective hydrolyses of acetylated monosaccharides
Tomic, Srdanka,Ljevakovic, Durjica,Tomasic, Jelka
, p. 10977 - 10986 (2007/10/02)
Deacylations of fully acylated D-glucopyranoses, methyl D-glucopyranosides, 2-acetamido-2-deoxy-D-glucopyranoses glucopyranoses and methyl 2-acetamido-2-deoxy-D-glucopyranosides catalyzed by rabbit serum or the esterase isolated from rabbit serum were investigated. Depending on the structure of the acyl protecting group a high degree of regioselectivity is observed. Products of enzymic hydrolysis followed by intramolecular migrations of acetyl groups are also described.
Novel methods for the preparation of partially acetylated carbohydrates
Hanessian, Stephen,Kagotani, Masahiro
, p. 67 - 79 (2007/10/02)
The selective acetylation of methyl α-D-hexopyranosides in the presence of zinc chloride shows unusual reactivity patterns compared to control experiments.Hydroperoxide ion is a mild and selective deacetylation reagent which does not attack primary acetates.
