87595-96-8

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 17184-28-0 Methyl-3,6-anhydro-α-D-glucofuranosid 
• 87638-78-6 3,6-anhydro-D-glucofuranose 
• 13407-60-8 methyl-3,6-anhydro-α-D-glucopyranoside 

Downstream Products

• 86883-39-8 Methyl-3,6-anhydro-5-O-tosyl-α-D-glucofuranosid 
• 87595-95-7 Methyl-2,5:3,6-dianhydro-α-D-mannofuranosid 
• 17184-28-0 Methyl-3,6-anhydro-α-D-glucofuranosid 

Relevant academic research and scientific papers

Carbohydrates Containing the 2,6-Dioxabicyclooctane Skeleton: 3,6-Anhydrohexofuranose Derivatives with D-gluco, D-manno, L-ido, and L-gulo Configuration

All possible 3,6-anhydrofuranoses as well as their triacetates, methyl glycosides, and methyl diacetylglycosides have been prepared, some of them for the first time.This allowed an analysis of the equilibria of the anomers of the free sugars in water and

Selective Tosylations of 3,6-Anhydrohexofuranosides with gluco, manno, and gulo Configuration

Selective monotosylation of methyl 3,6-anhydro-α-D-mannofuranoside (1a) preferentially yields the 5-O-tosylate 1e which opens via nucleophilic substitution access to β-L-gulo derivatives 2 by inversion of configuration at C-5.Analogously reaction of the d