87598-28-5

Upstream product

• 24734-68-7 3-Phenylpropane-1-thiol 
• 532-27-4 1-chloroacetophenone 

Downstream Products

• 100947-01-1 3,6-dihydro-6-methoxy-4-methyl-2-(2-phenylethyl)-6-<(trimethylsilyl)oxy>-2H-thiopyran 
• 100946-85-8 3,6-dihydro-4-<oxy>-2-(2-phenylethyl)-2H-thiopyran 
• 100946-86-9 3,6-dihydro-4-<oxy>-6-methoxy-2-(2-phenyl)-2H-thiopyran 
• 88358-54-7 2-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-phenethyl-[1,4,2]oxathiazolidine 
• 116233-89-7 3-(2-phenylethyl)-2-thiabicyclo<2.2.1>hept-5-ene 
• 100946-88-1 (1R,3S,4S)-3-Phenethyl-2-thia-bicyclo[2.2.1]hept-5-ene 
• 100946-88-1 (1S,3S,4R)-3-Phenethyl-2-thia-bicyclo[2.2.1]hept-5-ene 
• 88358-61-6 3-Methyl-5-phenethyl-[1,4,2]oxathiazole 
• 104-53-0 3-phenyl-propionaldehyde 
• 100947-02-2 4-methyl-6-(2-phenylethyl)tetrahydro-2H-thiopyran-2-one 
• 116233-76-2 2-Methyl-5-phenethyl-4-phenyl-2,5-dihydro-thiazole-2-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Thioaldehyde Diels-Alder Reactions

Thioaldehydes containing virtually any α-substitutent can be generated by photofragmentation of phenacyl sulfides.Donor-substituted derivatives are reactive toward electron-rich dienes and give 2 + 4 cycloadducts with regiochemistry corresponding to advan

A Method for Mild Photochemical Oxidation; Conversion of Phenacyl Sulfides into Carbonyl Compounds

Sunlamp irradiation of phenacyl sulfides PhCOCH2SCHRR' affords thiocarbonyl compounds S=CRR' that can be trapped in high yield by using the nitronate CH3CH=N+(OTBS)O-; the heterocycle 3 resulting from 1,3-dipolar cycloaddition is cleaved rapidly by fluoride ion to give ketones or aldehydes.