87604-56-6

Upstream product

• 61981-44-0 (2R, 3RS)-(+)-1,2,3-heptantriol-1,2-acetonide-3-benzyl ether 
• 108-94-1 cyclohexanone 
• 76779-67-4 1,2,5,6-di-O-cyclohexylidene-D-mannitol 
• 78008-36-3 (R)-2,3-cyclohexylideneglyceraldehyde 
• 87604-51-1 (R)-4-((S)-1-Benzyloxy-pentyl)-2,2-dimethyl-[1,3]dioxolane 
• 100-44-7 benzyl chloride 

Downstream Products

• 61981-46-2 Toluene-4-sulfonic acid (R)-3-benzyloxy-2-hydroxy-heptyl ester 
• 87604-60-2 (S)-(+)-2-benzyloxyhexan-1-ol 
• 6920-22-5 (2S)-hexane-1,2-diol 
• 87678-65-7 (S)-(-)-2-benzyloxyhexanal 

Relevant academic research and scientific papers

(R)-2,3-cyclohexylideneglyceraldehyde, a chiral pool synthon for the synthesis of 2-azido-1,3-diols

A new approach was proposed for the synthesis of 2-azido-1,3-diols from easily available and inexpensive chiral pool synthon (R)-2,3-O-cyclohexylidene-D-glyceraldehyde, through Mitsunobu azidation of 1,2-diols. Both C(2) and C(1) azides in variable ratios

ON THE STERIC COURSE OF THE ADDITION OF SOME ORGANOMETALLIC REAGENTS TO (R)-2,3-ISOPROPYLIDENE GLYCERALDEHYDE. SYNTHESIS OF OPTICALLY ACTIVE α-BENZYLOXY ALDEHYDES, ALCOHOLS, CARBOXYLIC ACIDS AND 1,2-DIOLS.

Organo-titanium and organo-zinc reagents were added stereoselectively to (R)-2,3-isopropylidene glyceraldehyde (1) to give the alcohols 2/3, which were converted into the optically active derivatives 4-11.