876366-16-4Relevant academic research and scientific papers
Enantioselective Palladium-Catalyzed Hydrophosphinylation of Allenes with Phosphine Oxides: Access to Chiral Allylic Phosphine Oxides
Wang, Jun,Yang, Zhiping
supporting information, p. 27288 - 27292 (2021/11/17)
A Pd-catalyzed hydrophosphinylation of alkyl and aryl-oxyallenes with phosphine oxides has been developed for the efficient and rapid construction of a family of chiral allylic phosphine oxides with a diverse range of functional groups. This methodology was further applied in the facile construction of chiral 2H-chromene and later stage functionalization of cholesterol.
Pd-Catalyzed Hydroamination of Alkoxyallenes with Azole Heterocycles: Examples and Mechanistic Proposal
Bernar, Ivan,Fiser, Béla,Blanco-Ania, Daniel,Gómez-Bengoa, Enrique,Rutjes, Floris P. J. T.
supporting information, p. 4211 - 4214 (2017/08/23)
Palladium-catalyzed regio- and enantioselective addition of azole heterocycles to alkoxyallenes was developed (up to 92% yields and up to 94% ee). DFT calculations suggest a new Pd(0)-driven mechanistic pathway proceeding through protonation of the Pd-coo
Synthesis of Fréchet type dendritic benzyl propargyl ether and Fréchet type triazole dendrimer
Lee, Jae Wook,Kim, Jung Hwan,Kim, Byung-Ku,Shin, Won Suk,Jin, Sung-Ho
, p. 894 - 900 (2007/10/03)
Fréchet type dendritic benzyl propargyl ethers were synthesized by the reaction of propargyl bromide with the corresponding Fréchet type dendritic benzyl alcohol. A propargyl focal point functionalized dendrons were applied for the construction of symmetr
